Issue 40, 2012

Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

Abstract

Two metal–organic frameworks containing barium were synthesized hydrothermally and investigated for their catalytic properties. Ba2F2[O3SC2H4SO3] has barium fluoride layers linked by organic 1,2-ethanedisulfonate molecules. Ba[O3SC2H4SO3] has discrete barium centers arranged in layers and connected covalently by ethanedisulfonate bridges. Thermogravimetric analysis showed that Ba2F2[O3SC2H4SO3] is stable to ca. 325 °C and Ba[O3SC2H4SO3] to ca. 375 °C. These materials expand the metal–organic frameworks available for group II metals bound to organodisulfonate linkers and are potentially useful for a range of heterogeneous acid catalysis reactions.

Graphical abstract: Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

Supplementary files

Article information

Article type
Paper
Submitted
10 Jul 2012
Accepted
28 Aug 2012
First published
31 Aug 2012

Dalton Trans., 2012,41, 12630-12634

Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

Y. Abdollahian, J. L. Hauser, D. L. Rogow, A. G. Oliver and S. R. J. Oliver, Dalton Trans., 2012, 41, 12630 DOI: 10.1039/C2DT31518A

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