Issue 48, 2012
From the journal:

Dalton Transactions

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids†

Sam Bullock,a   Andrew J. Hallett,b   Lindsay P. Harding,*a   Joshua J. Higginson,a   Sean A. F. Piela,a   Simon J. A. Popeb  and  Craig R. Ricea  

* Corresponding authors

a Department of Chemical & Biological Sciences, University of Huddersfield, Queensgate, Huddersfield, West Yorks, UK
E-mail: l.p.harding@hud.ac.uk
Fax: +44 (0)1484 472182
Tel: +44 (0)1484 472434

b School of Chemistry, Main Building, Cardiff University, Cardiff, UK

Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

Graphical abstract: Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

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Article information

DOI
https://doi.org/10.1039/C2DT31476B
Article type
Paper
Submitted
05 Jul 2012
Accepted
27 Sep 2012
First published
03 Oct 2012

Dalton Trans., 2012,41, 14690-14696

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Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

S. Bullock, A. J. Hallett, L. P. Harding, J. J. Higginson, S. A. F. Piela, S. J. A. Pope and C. R. Rice, Dalton Trans., 2012, 41, 14690 DOI: 10.1039/C2DT31476B

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