Issue 30, 2012
From the journal:

Dalton Transactions

Benzenepolycarboxylate-templated assembly of silver coordination polymers exhibiting argentophilic honeycomb layer and tubular motifs†

Bo Li,a   Can Ji,a   Shuang-Quan Zang,*a   Hong-Wei Houa  and  Thomas C. W. Makab  

* Corresponding authors

a The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China
E-mail: zangsqzg@zzu.edu.cn
Fax: (+86) 371-6778 0136
Tel: (+86) 371-6778 0136

b Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China

Abstract

Organic anion template-controlled reactions of benzenepolycarboxylic acids with silver(I) salts resulted in two coordination polymers with distinct structural features based on the argentophilic interaction, one exhibiting a honeycomb layer formed by the fusion of macrocyclic Ag16 rings and the other furnishing the first example of a Ag∞ tubular motif.

Graphical abstract: Benzenepolycarboxylate-templated assembly of silver coordination polymers exhibiting argentophilic honeycomb layer and tubular motifs

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Article information

DOI
https://doi.org/10.1039/C2DT31160G
Article type
Communication
Submitted
07 May 2012
Accepted
30 May 2012
First published
11 Jun 2012

Dalton Trans., 2012,41, 9151-9153

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Benzenepolycarboxylate-templated assembly of silver coordination polymers exhibiting argentophilic honeycomb layer and tubular motifs

B. Li, C. Ji, S. Zang, H. Hou and T. C. W. Mak, Dalton Trans., 2012, 41, 9151 DOI: 10.1039/C2DT31160G

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