The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

E. Berezovskaya; E. Milke; M. Binnewies

doi:10.1039/C2DT31058A

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The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb₂MO₆, Sb₂M₂O₉, Sb₂Mo₃O₁₂ and Sb₄MO₉ in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies†

E. Berezovskaya,*^a E. Milke^a and M. Binnewies^a

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* Corresponding authors

^a Institut für Anorganische Chemie, Leibniz Universität Hannover, Callinstr. 9, 30167 Hannover, Germany
E-mail: katja.berezovskaya@aca.uni-hannover.de
Fax: +49-0511-762-2254

Abstract

The ternary oxides Sb₂MO₆, Sb₂M₂O₉, Sb₄MO₉ (M = Mo, W) and Sb₂Mo₃O₁₂ were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.

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Article information

DOI: https://doi.org/10.1039/C2DT31058A
Article type: Paper
Submitted: 16 May 2012
Accepted: 06 Jul 2012
First published: 06 Jul 2012

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Dalton Trans., 2012,41, 10769-10776

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The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb₂MO₆, Sb₂M₂O₉, Sb₂Mo₃O₁₂ and Sb₄MO₉ in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

E. Berezovskaya, E. Milke and M. Binnewies, Dalton Trans., 2012, 41, 10769 DOI: 10.1039/C2DT31058A

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Dalton Transactions