Issue 26, 2012
From the journal:

Dalton Transactions

Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework†

Piyal W. G. Ariyananda,a   Glenn P. A. Yapa  and  Joel Rosenthal*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA
E-mail: rosenthal@mail.chem.udel.edu

Abstract

The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDCMes)PdMe2 towards CO2 has been investigated. In the presence of trace H2O, this reaction yields the corresponding methyl bicarbonate complex (MDCMes)PdMe(O2COH), which goes on to give the corresponding κ2-carbonato complex upon crystallization (MDCMes)Pd(CO3). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

Graphical abstract: Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

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Article information

DOI
https://doi.org/10.1039/C2DT30676J
Article type
Paper
Submitted
23 Mar 2012
Accepted
18 May 2012
First published
30 May 2012

Dalton Trans., 2012,41, 7977-7983

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Reaction of carbon dioxide with a palladium–alkyl complex supported by a bis-NHC framework

P. W. G. Ariyananda, G. P. A. Yap and J. Rosenthal, Dalton Trans., 2012, 41, 7977 DOI: 10.1039/C2DT30676J

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