Issue 33, 2012
From the journal:

Dalton Transactions

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor†

Claire Besson,ab   Sebastian Schmitz,a   Kimberly M. Capella,a   Sivil Kopilevich,c   Ira A. Weinstock*c  and  Paul Kögerler*ab  

* Corresponding authors

a Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de
Fax: +49 241-80-92642

b Peter Grünberg Institut, Forschungszentrum Jülich, 52425 Jülich, Germany

c Dept of Chemistry and Ilse Katz Institute for Nanoscale Science & Technology, Ben Gurion University, Beer Sheva, Israel
E-mail: iraw@bgu.ac.il

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid “guests” and azide functions previously attached to binding sites within the cavity of a {Mo132}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

Graphical abstract: A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

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Article information

DOI
https://doi.org/10.1039/C2DT30502J
Article type
Communication
Submitted
01 Mar 2012
Accepted
20 Jun 2012
First published
10 Jul 2012

Dalton Trans., 2012,41, 9852-9854

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A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

C. Besson, S. Schmitz, K. M. Capella, S. Kopilevich, I. A. Weinstock and P. Kögerler, Dalton Trans., 2012, 41, 9852 DOI: 10.1039/C2DT30502J

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