Issue 45, 2012

Assembly of a phospho-molybdic Wells–Dawson-based silver coordination polymer derived from Keggin polyoxoanion cluster

Abstract

A 2D Wells–Dawson-based silver(I) coordination polymer was achieved based on silver-Schiff base building blocks and [P2Mo18O62]6− clusters using AgNO3, N,N′-bis(furan-2-ylmethylene)hydrazine and Keggin [PMo12O40]3− as original materials at room temperature. It is structurally characterized by IR spectroscopy, 31P NMR, XRPD, thermogravimetric (TG) analyses and X-ray crystallography. The structure of 1 exhibits a novel crystalline 2D coordination polymer constructed by the coordination interaction between the Wells–Dawson polyoxoanion [P2Mo18O62]6− and Ag–L species. The luminescent property of 1 in the solid state is investigated.

Graphical abstract: Assembly of a phospho-molybdic Wells–Dawson-based silver coordination polymer derived from Keggin polyoxoanion cluster

Supplementary files

Article information

Article type
Paper
Submitted
28 Feb 2012
Accepted
07 Sep 2012
First published
10 Sep 2012

Dalton Trans., 2012,41, 13856-13861

Assembly of a phospho-molybdic Wells–Dawson-based silver coordination polymer derived from Keggin polyoxoanion cluster

D. Dang, B. An, Y. Bai and J. Niu, Dalton Trans., 2012, 41, 13856 DOI: 10.1039/C2DT30476G

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