Issue 19, 2012
From the journal:

Dalton Transactions

In situhydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst†

Li Liang,a   Guo Peng,a   Guizhu Li,a   Yanhua Lan,*b   Annie K. Powellb  and  Hong Deng*a  

* Corresponding authors

a School of Chemistry & Environment, South China Normal University; Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou 510006, P. R. China
E-mail: dh@scnu.edu.cn

b Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany
E-mail: yanhua.lan@kit.edu

Abstract

A family of six dinuclear lanthanide complexes have been obtained via in situ hydrothermal synthesis with lanthanide ions as catalyst. These six complexes are formulated as [Ln2(3-Htzba)2(3-tzba)2(H2O)8]·4H2O [Ln = Gd, 1; Dy, 2; Eu, 3; Tb, 4; Sm, 5; Er, 6; 3-H2tzba = 3-(1H-tetrazol-5-yl)benzoic acid]. The magnetic investigations show that complex 2 behaves as a single-molecule magnet (SMM) with a quantum relaxation time of ∼10−2 s.

Graphical abstract: In situ hydrothermal synthesis of dysprosium(iii) single-molecule magnet with lanthanide salt as catalyst

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Article information

DOI
https://doi.org/10.1039/C2DT30175J
Article type
Paper
Submitted
24 Jan 2012
Accepted
14 Feb 2012
First published
21 Feb 2012

Dalton Trans., 2012,41, 5816-5823

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In situ hydrothermal synthesis of dysprosium(III) single-molecule magnet with lanthanide salt as catalyst

L. Liang, G. Peng, G. Li, Y. Lan, A. K. Powell and H. Deng, Dalton Trans., 2012, 41, 5816 DOI: 10.1039/C2DT30175J

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