Issue 12, 2012
From the journal:

Dalton Transactions

Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]†

Delphine Crozet,a   David McKay,b   Christian Bijani,c   Aitor Gual,d   Cyril Godard,d   Carmen Claver,d   Laurent Maron,b   Martine Urrutigoïty*a  and  Philippe Kalck*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination UPR CNRS 8241, composante ENSIACET, Université de Toulouse UPS-INP-LCC, 4 allée Emile Monso BP 44362, 31030 Toulouse Cedex 4, France
E-mail: philippe.kalck@ensiacet.fr

b LPCNO, UMR 5215, Université de Toulouse-CNRS, INSA, UPS, 135 avenue de Rangueil, F-31077 Toulouse Cedex 4, France

c Laboratoire de Chimie de Coordination, CNRS UPR 8241, Université de Toulouse UPS-INP-LCC, 205, route de Narbonne, 31077 cedex 04, France

d Departament de Quimica Fisica i Inorganica, Universitat Rovira i Virgili, C/Marcel·li Domingo s/n, 43007 Tarragona, Spain

Abstract

Reaction of [Rh(CO)2{(R,R)-Ph–BPE}][BF4] 1 under 7 bar H2 provides the dihydride [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 3, which reacts with the neutral hydride [Rh(H)(CO){(R,R)-Ph–BPE}] 2 arising from 3 in THF. The resulting complex is the dimeric monocationic Rh(I)–Rh(III) complex [Rh(H)2(CO)2{(R,R)-Ph–BPE}][BF4] 4.

Graphical abstract: Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

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DOI
https://doi.org/10.1039/C2DT12400A
Article type
Communication
Submitted
12 Dec 2011
Accepted
27 Jan 2012
First published
31 Jan 2012

Dalton Trans., 2012,41, 3369-3373

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Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

D. Crozet, D. McKay, C. Bijani, A. Gual, C. Godard, C. Claver, L. Maron, M. Urrutigoïty and P. Kalck, Dalton Trans., 2012, 41, 3369 DOI: 10.1039/C2DT12400A

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