Issue 15, 2012
From the journal:

Dalton Transactions

Didocosyl selenide stabilized recyclable Pd(0) nanoparticles and coordinated palladium(ii) as efficient catalysts for Suzuki–Miyaura coupling†

Gyandshwar Kumar Rao,a   Arun Kumar,a   Bharat Kumara  and  Ajai K. Singh*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110016, India
E-mail: aksingh@chemistry.iitd.ac.in, ajai57@hotmail.com
Fax: +91 11 26581102
Tel: +91 11 26591379

Abstract

First selenium ligand stabilized Pd(0) nanoparticles (∼3–5 nm) catalyze Suzuki–Miyaura C–C coupling in short time and are recyclable (up to 94% yield after 5 reuses). The air stable compound [PdCl2(L1)2] shows high catalytic efficiency for this coupling as its 3 × 10−5 mol% is sufficient for activated ArBr.

Graphical abstract: Didocosyl selenide stabilized recyclable Pd(0) nanoparticles and coordinated palladium(ii) as efficient catalysts for Suzuki–Miyaura coupling

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Article information

DOI
https://doi.org/10.1039/C2DT12256A
Article type
Communication
Submitted
25 Nov 2011
Accepted
02 Feb 2012
First published
29 Feb 2012

Dalton Trans., 2012,41, 4306-4309

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Didocosyl selenide stabilized recyclable Pd(0) nanoparticles and coordinated palladium(II) as efficient catalysts for Suzuki–Miyaura coupling

G. Kumar Rao, A. Kumar, B. Kumar and A. K. Singh, Dalton Trans., 2012, 41, 4306 DOI: 10.1039/C2DT12256A

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