Issue 8, 2012
From the journal:

Dalton Transactions

Synthesis and characterization of a ferrocene-linked bis-fullerene[60] dumbbell†

Claes-Henrik Andersson,a   Leif Nyholmb  and  Helena Grennberg*a  

* Corresponding authors

a Uppsala University, Dept. of Biochemistry and Organic Chemistry, Box 576, Uppsala, Sweden
E-mail: Helena.Grennberg@Biorg.uu.se
Fax: +46-18-4713818

b Dept. of Materials Chemistry, Uppsala University, Box 538, Uppsala, Sweden

Abstract

A new [60]fullerene dumbbell consisting of two fulleropyrrolidines connected to a central ferrocene unit by amide linkages has been prepared and fully characterized by elemental analysis, 1H NMR, UV/Vis, fluorescence and mass spectrometry. The electrochemical properties as determined by cyclic voltammetry show ground state electronic communication between the ferrocene and the fullerene units. In addition, the preparaton of a ferrocene building block for an alternative linking approach is presented.

Graphical abstract: Synthesis and characterization of a ferrocene-linked bis-fullerene[60] dumbbell

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Article information

DOI
https://doi.org/10.1039/C2DT12097F
Article type
Paper
Submitted
03 Nov 2011
Accepted
22 Nov 2011
First published
04 Jan 2012

Dalton Trans., 2012,41, 2374-2381

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Synthesis and characterization of a ferrocene-linked bis-fullerene[60] dumbbell

C. Andersson, L. Nyholm and H. Grennberg, Dalton Trans., 2012, 41, 2374 DOI: 10.1039/C2DT12097F

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