Auxiliary ligand induced structural allomorphism in nanotubular microporous metal–organic frameworks based on discrete magnesium clusters†
Abstract
Three allomorphs with the same stoichiometry, [Mg3(H2O)4(5-aip)2(5-Haip)2]·4DMA, were solvothermally synthesized in the presence of different additives and represented the first 8-connected nanotubular networks in Mg-based metal–organic frameworks. The