Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 21st October 2020 from 07:00 AM to 07:00 PM (BST).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 26, 2012
Previous Article Next Article

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

Author affiliations

Abstract

Phosphinoamide ligands have been utilized to link a CoI center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph2PNiPr)3M[double bond, length as m-dash]NtBu, have weakened dative metal–metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.

Graphical abstract: Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)

Back to tab navigation

Supplementary files

Article information


Submitted
05 Jan 2012
Accepted
24 Feb 2012
First published
28 Feb 2012

Dalton Trans., 2012,41, 8111-8115
Article type
Paper

Synthesis and investigation of the metal–metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(I)

D. A. Evers, A. H. Bluestein, B. M. Foxman and C. M. Thomas, Dalton Trans., 2012, 41, 8111
DOI: 10.1039/C2DT00034B

Social activity

Search articles by author

Spotlight

Advertisements