Issue 19, 2012
From the journal:

Dalton Transactions

A novel polyoxovanadium borate incorporating an organic amineligand: synthesis and structure of [V12B16O50(OH)7(en)]7−†‡§

Yan-Qiong Sun,a   Guang-Man Lia  and  Yi-Ping Chen*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China
E-mail: ypchen007@sina.com
Fax: +86-591-22866340

Abstract

A novel 1D chain organic–inorganic hybrid polyoxovanadium borate Na[V12B16O50(OH)7(en)]2(enH2)6(enH)2(OH)(H2O)19 (1, en = ethylenediamine), based on a [V12B16O50(OH)7(en)]7− cluster unit, has been hydrothermally synthesized and characterized. Interestingly, organic amine is incorporating into the V12B16 clusters.

Graphical abstract: A novel polyoxovanadium borate incorporating an organic amine ligand: synthesis and structure of [V12B16O50(OH)7(en)]7−

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Article information

DOI
https://doi.org/10.1039/C2DT00018K
Article type
Communication
Submitted
04 Jan 2012
Accepted
24 Mar 2012
First published
28 Mar 2012

Dalton Trans., 2012,41, 5774-5777

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A novel polyoxovanadium borate incorporating an organic amine ligand: synthesis and structure of [V12B16O50(OH)7(en)]7−

Y. Sun, G. Li and Y. Chen, Dalton Trans., 2012, 41, 5774 DOI: 10.1039/C2DT00018K

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