Issue 5, 2012
From the journal:

Dalton Transactions

Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination†

Alessia Famengo,ab   Dalice Pinero,a   Olivier Jeannin,*a   Thierry Guizouarna  and  Marc Fourmigué*a  

* Corresponding authors

a Sciences Chimiques de Rennes, Université Rennes 1, CNRS UMR 6226, Campus de Beaulieu, 35042 Rennes, France
E-mail: marc.fourmigue@univ-rennes1.fr, olivier.jeannin@univ-rennes1.fr

b Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via Marzolo 1, 35131 Padova, Italy

Abstract

The secondary coordination ability of a paramagnetic nickel dithiolene complex, bearing an ether coordinating function within a nine-membered flexible ring, has been demonstrated in its [NiCl(DMF)2]+ complex, through coordination by both ether and thioether functions, allowing for a ferromagnetic interaction between both paramagnetic entities.

Graphical abstract: Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination

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Article information

DOI
https://doi.org/10.1039/C1DT12028J
Article type
Communication
Submitted
25 Oct 2011
Accepted
15 Nov 2011
First published
06 Dec 2011

Dalton Trans., 2012,41, 1441-1443

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Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination

A. Famengo, D. Pinero, O. Jeannin, T. Guizouarn and M. Fourmigué, Dalton Trans., 2012, 41, 1441 DOI: 10.1039/C1DT12028J

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