Issue 11, 2012

Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles

Abstract

The reaction of sodium perfluoro-tert-butoxide with benzylic carbon–bromide bond(s) leads to the formation of (nonafluoro-tert-butoxy)methyl ponytail(s), which can enhance the fluorous solubility and partition of aromatics and heterocycles.

Graphical abstract: Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles

Supplementary files

Article information

Article type
Paper
Submitted
02 Oct 2011
Accepted
05 Dec 2011
First published
16 Jan 2012

Phys. Chem. Chem. Phys., 2012,14, 3909-3914

Generation of (nonafluoro-tert-butoxy)methyl ponytails for enhanced fluorous partition of aromatics and heterocycles

X. Zhao, W. Y. Ng, K. Lau, A. E. C. Collis and I. T. Horváth, Phys. Chem. Chem. Phys., 2012, 14, 3909 DOI: 10.1039/C2CP23113A

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