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Issue 23, 2012
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A metal–organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

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Abstract

Reaction of the asymmetric ligand, 1-[3′-(1,2,4-triazol-4-yl)propyl]tetrazole (L) with Cu(BF4)2 in water leads to the CuII metal–organic framework [CuL(OH)]BF4 (I). According to X-ray analysis, L connects four CuII ions, where the 1,2,4-triazole and tetrazole units exhibit a bridging bis-monodentate μ2-N1,N2 and a unique μ2-N2,N3 coordination modes, respectively.

Graphical abstract: A metal–organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

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Article information


Submitted
06 Aug 2012
Accepted
13 Sep 2012
First published
01 Oct 2012

CrystEngComm, 2012,14, 8153-8155
Article type
Paper

A metal–organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

Y. Boland, B. Tinant, D. A. Safin, J. Marchand-Brynaert, R. Clérac and Y. Garcia, CrystEngComm, 2012, 14, 8153
DOI: 10.1039/C2CE26257F

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