A 6-fold interpenetrated ThSi2 topological metal–organic framework from a nanosized tripodal aromatic acid

Chunhua Ma; Yong Wu; Jun Zhang; Yan Xu; Beibei Tu; Yaoming Zhou; Min Fang; Hong-Ke Liu

doi:10.1039/C2CE25422K

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A 6-fold interpenetrated ThSi₂ topological metal–organic framework from a nanosized tripodal aromatic acid†

Chunhua Ma,^a Yong Wu,^a Jun Zhang,^bd Yan Xu,^c Beibei Tu,^a Yaoming Zhou,^a Min Fang*^a and Hong-Ke Liu*^a

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* Corresponding authors

^a Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Material Science, Nanjing Normal University, Nanjing, China
E-mail: liuhongke@njnu.edu.cn, fangmin@njnu.edu.cn
Tel: +86-2585891949

^b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

^c College of chemistry and chemical engineering, Nanjing University of Technology, Nanjing, China

^d School of Materials and Chemical Engineering, Anhui University of Architecture, Hefei, 230601, China

Abstract

A unique anionic 6-fold interpenetrated (10,3)-b Cd(II) framework was obtained using a novel nanosized tripodal aromatic acid ligand, in which both the Cd(II) atoms and tripodal aromatic acid ligands act as three-connected nodes. This compound displays intense and blue-shifted photoluminescence compared to that of the free H₃L ligand.

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Article information

DOI: https://doi.org/10.1039/C2CE25422K
Article type: Communication
Submitted: 23 Mar 2012
Accepted: 17 May 2012
First published: 02 Jul 2012

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CrystEngComm, 2012,14, 5166-5169

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A 6-fold interpenetrated ThSi₂ topological metal–organic framework from a nanosized tripodal aromatic acid

C. Ma, Y. Wu, J. Zhang, Y. Xu, B. Tu, Y. Zhou, M. Fang and H. Liu, CrystEngComm, 2012, 14, 5166 DOI: 10.1039/C2CE25422K

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