Topotactic transformation of single-crystalline TiOF2 nanocubes to ordered arranged 3D hierarchical TiO2 nanoboxes

Zeyan Wang; Baibiao Huang; Ying Dai; Xiaoyang Zhang; Xiaoyan Qin; Zhao Li; Zhaoke Zheng; Hefeng Cheng; Liwen Guo

doi:10.1039/C2CE25271F

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Topotactic transformation of single-crystalline TiOF₂ nanocubes to ordered arranged 3D hierarchical TiO₂ nanoboxes†

Zeyan Wang,^a Baibiao Huang,*^a Ying Dai,^b Xiaoyang Zhang,^a Xiaoyan Qin,^a Zhao Li,^a Zhaoke Zheng,^a Hefeng Cheng^a and Liwen Guo^a

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* Corresponding authors

^a State Key Laboratory of Crystal Materials, Shanda Nan Road 27, Jinan, China
E-mail: bbhuang@sdu.edu.cn
Fax: (+86) 531-8836-5969
Tel: (+86) 531-8836-4449

^b School of Physics, Shandong University, Shanda Nan Road 27, Jinan, China

Abstract

3D hierarchical TiO₂ nanoboxes, enclosed by six ordered arranged TiO₂ nanorod arrays, were prepared via a template-engaged topotactic transformation process from TiOF₂ nanocubes. The lattice matching between TiOF₂ and anatase TiO₂ was regarded as the key for the preferential growth and ordered arrangement of the TiO₂ nanorods.

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Article information

DOI: https://doi.org/10.1039/C2CE25271F
Article type: Communication
Submitted: 24 Feb 2012
Accepted: 18 Apr 2012
First published: 19 Apr 2012

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CrystEngComm, 2012,14, 4578-4581

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Topotactic transformation of single-crystalline TiOF₂ nanocubes to ordered arranged 3D hierarchical TiO₂ nanoboxes

Z. Wang, B. Huang, Y. Dai, X. Zhang, X. Qin, Z. Li, Z. Zheng, H. Cheng and L. Guo, CrystEngComm, 2012, 14, 4578 DOI: 10.1039/C2CE25271F

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