Issue 16, 2012
From the journal:

CrystEngComm

An unusual (4,10)-connected 3-D metal–organic framework based on non-planar tricarboxyl tecton and tetracadmium(ii) secondary building units†

Shao-Ming Fang,a   Min Chen,a   Xiao-Gang Yang,a   Cong Wang,a   Miao Du*b  and  Chun-Sen Liu*a  

* Corresponding authors

a Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou, Henan, P. R. China
E-mail: chunsenliu@zzuli.edu.cn (C.-S.L.)

b College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin, P. R. China
E-mail: dumiao@public.tpt.tj.cn (M.D.)

Abstract

A new Cd(II) coordination polymer [Cd4(μ3-OH)2(L)2(H2O)3]n (1) is constructed from an unexplored non-planar trigonal tricarboxyl ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L), which exhibits an unusual (4,10)-connected (3.45)(34.49.512.617.72.8) topological net based on the tetranuclear [Cd4(μ3-OH)2] secondary building units (SBUs). The elaborate modification of organic tectons provides a new perspective on the design and synthesis of highly-connected coordination networks. Additionally, the thermal stability and luminescence of the crystalline material have also been investigated.

Graphical abstract: An unusual (4,10)-connected 3-D metal–organic framework based on non-planar tricarboxyl tecton and tetracadmium(ii) secondary building units

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Article information

DOI
https://doi.org/10.1039/C2CE25194A
Article type
Paper
Submitted
12 Feb 2012
Accepted
01 Jun 2012
First published
06 Jun 2012

CrystEngComm, 2012,14, 5299-5304

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An unusual (4,10)-connected 3-D metal–organic framework based on non-planar tricarboxyl tecton and tetracadmium(II) secondary building units

S. Fang, M. Chen, X. Yang, C. Wang, M. Du and C. Liu, CrystEngComm, 2012, 14, 5299 DOI: 10.1039/C2CE25194A

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