Solvent influences structural variation from a 3D 4-fold interpenetrated framework to a 2D layer-type porous coordination polymer: Structure analysis and highly selective gas adsorption properties†
Abstract
Two new complexes {[Co(dcpy)(bipy)0.5]·H2O} (1) and {[Co(dcpy)(bipy)0.5(H2O)]·2H2O} (2) constructed from the same initial materials Co(NO3)2·6H2O, 3-(2′,5′-dicarboxylphenyl)pyridine (H2dcpy) and