Issue 2, 2012
From the journal:

CrystEngComm

Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2†

Maria G. Babashkina,a   Damir A. Safin,*a   Monika Srebro,b   Piotr Kubisiak,b   Mariusz P. Mitoraj,b   Michael Boltec  and  Yann Garciaa  

* Corresponding authors

a Institute of Condensed Matter and Nanosciences, MOST - Inorganic Chemistry, Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium
E-mail: damir.safin@ksu.ru
Fax: +32(0) 1047 2330
Tel: +32(0) 1047 2831

b Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060 Cracow, Poland

c Institut für Anorganische Chemie J.-W.-Goethe-Universität, Frankfurt/Main, Germany

Abstract

The reaction of the deprotonated N-thiophosphorylated thiourea 6-MeO(O)CC6H4NHC(S)NHP(S)(OiPr)2 (HL) with NiCl2 leads to violet [NiL22]·CH22Cl22 crystals, which were isolated by recrystallization from a mixture of CH2Cl2 and n-hexane. It was established that the deprotonated ligands, L, are 1,5-S,S′-coordinated. The influence of CH2Cl2 for the complex stabilization was studied.

Graphical abstract: Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CE06322G
Article type
Communication
Submitted
05 Oct 2011
Accepted
10 Nov 2011
First published
29 Nov 2011

CrystEngComm, 2012,14, 370-373

Permissions

Request permissions

Influence of CH2Cl2 for the structure stabilization of the NiII complex [Ni{6-MeO(O)CC6H4NHC(S)NP(S)(OiPr)2-1,5-S,S′}2]·CH2Cl2

M. G. Babashkina, D. A. Safin, M. Srebro, P. Kubisiak, M. P. Mitoraj, M. Bolte and Y. Garcia, CrystEngComm, 2012, 14, 370 DOI: 10.1039/C1CE06322G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements