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Issue 87, 2012
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Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

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Abstract

For the first time, intramolecular allylic amination was conducted using rhodium(III) according to an “inner-sphere” type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp3)–H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.

Graphical abstract: Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

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Article information


Submitted
21 Aug 2012
Accepted
10 Sep 2012
First published
28 Sep 2012

Chem. Commun., 2012,48, 10745-10747
Article type
Communication

Rhodium(III)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

T. Cochet, V. Bellosta, D. Roche, J. Ortholand, A. Greiner and J. Cossy, Chem. Commun., 2012, 48, 10745
DOI: 10.1039/C2CC36067E

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