Issue 89, 2012
From the journal:

Chemical Communications

Formal C–H amination of cyclopropenes†

Chunrui Sun,‡a   Jingwei Li,‡a   Daesung Lee,*a   Genping Huangb  and  Yuanzhi Xia*b  

* Corresponding authors

a Department of Chemistry, University of Illinois at Chicago, Chicago, USA
E-mail: dsunglee@uic.edu
Tel: +1-312-996-5189

b College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, PR China
E-mail: xyz@wzu.edu.cn

Abstract

A novel C(sp3)–H amination of trimethylsilyl-substituted cyclopropenes is described. This C–H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.

Graphical abstract: Formal C–H amination of cyclopropenes

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Article information

DOI
https://doi.org/10.1039/C2CC35329F
Article type
Communication
Submitted
24 Jul 2012
Accepted
20 Sep 2012
First published
24 Sep 2012

Chem. Commun., 2012,48, 10990-10992

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Formal C–H amination of cyclopropenes

C. Sun, J. Li, D. Lee, G. Huang and Y. Xia, Chem. Commun., 2012, 48, 10990 DOI: 10.1039/C2CC35329F

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