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Issue 71, 2012
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Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

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Abstract

We report Arbuzov-type reactions of chlorofullerene C60Cl6 with trialkyl phosphites producing highly functionalized fullerene derivatives C60[P(O)(OR)2]5H with high yields. The designed family of [60]fullerene phosphonic acids and their esters showed unusual properties which might find valuable material science applications.

Graphical abstract: Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

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Publication details

The article was received on 06 May 2012, accepted on 12 Jul 2012 and first published on 12 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34338J
Chem. Commun., 2012,48, 8916-8918

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    Arbuzov chemistry with chlorofullerene C60Cl6: a powerful method for selective synthesis of highly functionalized [60]fullerene derivatives

    A. A. Yurkova, E. A. Khakina, S. I. Troyanov, A. Chernyak, L. Shmygleva, A. S. Peregudov, V. M. Martynenko, Y. A. Dobrovolskiy and P. A. Troshin, Chem. Commun., 2012, 48, 8916
    DOI: 10.1039/C2CC34338J

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