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Issue 78, 2012
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A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIV single-chain magnets

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Abstract

A new cyanido-bridged ReIV–MnIII heterometallic 1D system, [MnIII(5-Me-saltmen)]2[ReIVCl4(CN)2]·3CH3CN (1), was designed and structurally characterized. Interchain interactions stabilize a canted antiferromagnetic ordered state below 6.2 K that does not prevent slow relaxation of the magnetization reminiscent of the single-chain magnet properties of the individual chains.

Graphical abstract: A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIV single-chain magnets

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Article information


Submitted
06 Jun 2012
Accepted
07 Aug 2012
First published
09 Aug 2012

Chem. Commun., 2012,48, 9717-9719
Article type
Communication

A canted antiferromagnetic ordered phase of cyanido-bridged MnIII2ReIV single-chain magnets

I. Bhowmick, E. A. Hillard, P. Dechambenoit, C. Coulon, T. D. Harris and R. Clérac, Chem. Commun., 2012, 48, 9717
DOI: 10.1039/C2CC34066F

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