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Issue 80, 2012
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First magnets based on thiocyanato-bridges

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2-D NCS-bridged {3d–4d} molecule-based magnets, formed by reaction of [MoIII(NCS)6]3− with either NiII or CoII complexes, have been found to exhibit magnetic ordering with TC = 39 K for {Co3Mo2} while {Ni3Mo2} has a non-magnetic ground state as a result of exact compensation by the individual sub-lattices.

Graphical abstract: First magnets based on thiocyanato-bridges

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The article was received on 30 May 2012, accepted on 22 Aug 2012 and first published on 04 Sep 2012

Article type: Communication
DOI: 10.1039/C2CC33877G
Citation: Chem. Commun., 2012,48, 10028-10030

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    First magnets based on thiocyanato-bridges

    M. Mousavi, V. Béreau, C. Duhayon, P. Guionneau and J. Sutter, Chem. Commun., 2012, 48, 10028
    DOI: 10.1039/C2CC33877G

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