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Issue 63, 2012
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Stereoselective intermolecular C–H amination reactions

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Abstract

A novel chiral N-mesyloxycarbamate to perform rhodium-catalyzed stereoselective C–H amination reactions is reported. Chiral benzylic and propargylic amines are produced in good yields and selectivities using ethyl acetate as solvent. The corresponding free amines are easily obtained by cleavage of the chiral reagent, which could also be recovered.

Graphical abstract: Stereoselective intermolecular C–H amination reactions

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Publication details

The article was received on 23 May 2012, accepted on 08 Jun 2012 and first published on 13 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33689H
Chem. Commun., 2012,48, 7799-7801

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    Stereoselective intermolecular C–H amination reactions

    H. Lebel, C. Trudel and C. Spitz, Chem. Commun., 2012, 48, 7799
    DOI: 10.1039/C2CC33689H

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