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Issue 67, 2012
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Redox switching of the antiferromagnetic coupling in permethylated dicopper(II) paracyclophanes

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Abstract

A unique magnetic electroswitching behavior has been observed in an oxamato-based permethylated dicopper(II) paracyclophane; upon reversible one-electron oxidation of the double tetramethyl-substituted p-phenylenediamidate bridging skeleton, the spin alignment of the two CuII ions (SCu = ½) changes from antiparallel (OFF) to parallel (ON) in the resulting dicopper(II) π-radical cation species.

Graphical abstract: Redox switching of the antiferromagnetic coupling in permethylated dicopper(ii) paracyclophanes

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Publication details

The article was received on 10 May 2012, accepted on 21 Jun 2012 and first published on 22 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33385F
Citation: Chem. Commun., 2012,48, 8401-8403

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    Redox switching of the antiferromagnetic coupling in permethylated dicopper(II) paracyclophanes

    J. Ferrando-Soria, M. Castellano, R. Ruiz-García, J. Cano, M. Julve, F. Lloret, J. Pasán, C. Ruiz-Pérez, L. Cañadillas-Delgado, Y. Li, Y. Journaux and E. Pardo, Chem. Commun., 2012, 48, 8401
    DOI: 10.1039/C2CC33385F

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