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Issue 74, 2012
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Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: unprecedented enhancement of enantiodiscrimination

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Abstract

Phosphorus dendrimers containing terminal phosphoramidite ligands have been found to be highly effective and recoverable catalysts for the rhodium(I) catalyzed [2+2+2] cycloaddition reactions. A strong positive dendritic effect is observed both in the activity and enantiodiscrimination leading to axially chiral biaryl compounds.

Graphical abstract: Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: unprecedented enhancement of enantiodiscrimination

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Publication details

The article was received on 26 Apr 2012, accepted on 31 Jul 2012 and first published on 08 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC32992A
Citation: Chem. Commun., 2012,48, 9248-9250
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    Dendritic phosphoramidite ligands for Rh-catalyzed [2+2+2] cycloaddition reactions: unprecedented enhancement of enantiodiscrimination

    L. Garcia, A. Roglans, R. Laurent, J. Majoral, A. Pla-Quintana and A. Caminade, Chem. Commun., 2012, 48, 9248
    DOI: 10.1039/C2CC32992A

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