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Issue 47, 2012
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An inorganic propellane with central B–B bond

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Abstract

9,10-Dihydroanthracene-9,10-diyl-bridged B2(NMe2)2 readily adds [H2NMe2]+, HCl and F3CCOOH across its partial B[double bond, length as m-dash]N double bond(s), thereby forming mono- or diadducts; treatment with 1-iso-propyl-2-mercaptoimidazole leads to a triply B–B-bridged propellane-like structure.

Graphical abstract: An inorganic propellane with central B–B bond

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Article information


Submitted
28 Mar 2012
Accepted
23 Apr 2012
First published
24 Apr 2012

Chem. Commun., 2012,48, 5886-5888
Article type
Communication

An inorganic propellane with central B–B bond

S. Pospiech, S. Brough, M. Bolte, H. Lerner, H. F. Bettinger and M. Wagner, Chem. Commun., 2012, 48, 5886
DOI: 10.1039/C2CC32256K

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