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Issue 45, 2012
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Dampened circumrotation by CH⋯π interactions in hydrogen bonded [2]rotaxanes

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Abstract

Establishment of CH⋯π interactions between the aliphatic axis and the benzylic amide macrocycle of hydrogen-bonded [2]rotaxanes causes a measurable interference in the pirouetting submolecular motion of these interlocked molecules.

Graphical abstract: Dampened circumrotation by CH⋯π interactions in hydrogen bonded [2]rotaxanes

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Article information


Submitted
22 Mar 2012
Accepted
10 Apr 2012
First published
11 Apr 2012

Chem. Commun., 2012,48, 5677-5679
Article type
Communication

Dampened circumrotation by CH⋯π interactions in hydrogen bonded [2]rotaxanes

J. Berná, M. Alajarín, J. S. Martínez-Espín, L. Buriol, M. A. P. Martins and R. Orenes, Chem. Commun., 2012, 48, 5677
DOI: 10.1039/C2CC32092D

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