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Issue 26, 2012
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Enantioselective carbonylene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

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Abstract

An asymmetric multicomponent catalyst, BINOLate/titanium, successfully encapsulated in the nanocages of mesoporous silicas exhibits much higher activity than the homogeneous counterpart in quasi solvent-free enantioselective carbonylene reaction, owing to the confinement effect of the nanoreactor.

Graphical abstract: Enantioselective carbonyl–ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

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Publication details

The article was received on 20 Dec 2011, accepted on 30 Jan 2012 and first published on 01 Feb 2012


Article type: Communication
DOI: 10.1039/C2CC17950D
Citation: Chem. Commun., 2012,48, 3191-3193
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    Enantioselective carbonylene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

    X. Liu, S. Bai, Y. Yang, B. Li, B. Xiao, C. Li and Q. Yang, Chem. Commun., 2012, 48, 3191
    DOI: 10.1039/C2CC17950D

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