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Issue 45, 2012
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Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square

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Abstract

The self-assembly of [FeIII(Tp)(CN)3] and [FeII(bik)2(S)2]2+ affords the cyanide-bridged mixed valence {FeIII2FeII2}2+ molecular square, which exhibits a photomagnetic effect under laser light irradiation at low temperature and also shows thermal spin-state conversion near ambient temperature.

Graphical abstract: Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square

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Publication details

The article was received on 14 Dec 2011, accepted on 13 Apr 2012 and first published on 16 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC17835D
Citation: Chem. Commun., 2012,48, 5653-5655
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    Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square

    A. Mondal, Y. Li, P. Herson, M. Seuleiman, M. Boillot, E. Rivière, M. Julve, L. Rechignat, A. Bousseksou and R. Lescouëzec, Chem. Commun., 2012, 48, 5653
    DOI: 10.1039/C2CC17835D

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