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Issue 29, 2012
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Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

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Abstract

Increasing dimensionality [from 2D (1) to 3D (2)] and TC [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic MnII2CuII3 open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.

Graphical abstract: Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

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Publication details

The article was received on 12 Dec 2011, accepted on 14 Feb 2012 and first published on 15 Feb 2012


Article type: Communication
DOI: 10.1039/C2CC17767F
Citation: Chem. Commun., 2012,48, 3539-3541

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    Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

    J. Ferrando-Soria, T. Grancha, M. Julve, J. Cano, F. Lloret, Y. Journaux, J. Pasán, C. Ruiz-Pérez and E. Pardo, Chem. Commun., 2012, 48, 3539
    DOI: 10.1039/C2CC17767F

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