Jump to main content
Jump to site search

Issue 23, 2012
Previous Article Next Article

Evidence for a reactive (alkene)peroxoiridium(iii) intermediate in the oxidation of an alkene complex with O2

Author affiliations

Abstract

An (alkene)peroxoiridium(III) complex, [Ir(L)(cod)(O2)] [where LH = PhN[double bond, length as m-dash]C(NMe2)NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the IrI precursor [Ir(L)(cod)] with O2 and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one.

Graphical abstract: Evidence for a reactive (alkene)peroxoiridium(iii) intermediate in the oxidation of an alkene complex with O2

Back to tab navigation

Supplementary files

Article information


Submitted
24 Nov 2011
Accepted
12 Jan 2012
First published
07 Feb 2012

Chem. Commun., 2012,48, 2876-2878
Article type
Communication

Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2

M. R. Kelley and J. Rohde, Chem. Commun., 2012, 48, 2876
DOI: 10.1039/C2CC17332H

Social activity

Search articles by author

Spotlight

Advertisements