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Issue 97, 2012

Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

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Abstract

Imines are selectively formed by coupling of nitriles and amines under mild hydrogen pressure. The reaction is catalyzed by a bipyridine-based PNN Ru(II) pincer complex and proceeds under mild, neutral conditions at 4 bar of H2.

Graphical abstract: Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

Supplementary files

Article information


Submitted
12 Sep 2012
Accepted
12 Oct 2012
First published
02 Nov 2012

Chem. Commun., 2012,48, 11853-11855
Article type
Communication

Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

D. Srimani, M. Feller, Y. Ben-David and D. Milstein, Chem. Commun., 2012, 48, 11853 DOI: 10.1039/C2CC36639H

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