Issue 97, 2012
From the journal:

Chemical Communications

Proton–electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols†

Riccardo Amorati,*a   Stefano Menichetti,b   Caterina Viglianisib  and  Mario C. Foti*c  

* Corresponding authors

a Department of Chemistry “Ciamician”, University of Bologna, Via San Giacomo 11, Bologna, Italy
E-mail: riccardo.amorati@unibo.it
Fax: +39 051 209 5688
Tel: +39 051 209 5689

b Department of Chemistry “U. Schiff”, University of Firenze, Via della Lastruccia, 3-13, Sesto Fiorentino, Italy

c Istituto di Chimica Biomolecolare, Consiglio Nazionale delle Ricerche, Via Paolo Gaifami, 18, Catania, Italy
E-mail: mario.foti@cnr.it
Fax: +39 095 733 8310
Tel: +39 095 733 8343

Abstract

The kinetics of the reaction of peroxyl and dpph˙ radicals with phenols H-bonded to N-bases have been studied for the first time. Electron-transfer processes are observed in MeCN but only with the dpph˙ radical.

Graphical abstract: Proton–electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols

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Article information

DOI
https://doi.org/10.1039/C2CC36531F
Article type
Communication
Submitted
07 Sep 2012
Accepted
24 Oct 2012
First published
24 Oct 2012

Chem. Commun., 2012,48, 11904-11906

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Proton–electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols

R. Amorati, S. Menichetti, C. Viglianisi and M. C. Foti, Chem. Commun., 2012, 48, 11904 DOI: 10.1039/C2CC36531F

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