Issue 96, 2012
From the journal:

Chemical Communications

Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway†

Jian Wang,a   Shan Wang,a   Gao Wang,a   Ji Zhang*a  and  Xiao-Qi Yu*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, P.R.China
E-mail: xqyu@scu.edu.cn
Fax: +86 28-8541-5886

Abstract

A novel iron-mediated direct C–H arylation of quinones and pyridine analogues with arylboronic acids has been developed using dichloromethane and water as solvents at ambient temperature. FeS is employed and serves as an efficient catalyst. A detailed reaction mechanism is speculated and expounded.

Graphical abstract: Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

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Article information

DOI
https://doi.org/10.1039/C2CC35468C
Article type
Communication
Submitted
28 Jul 2012
Accepted
20 Oct 2012
First published
22 Oct 2012

Chem. Commun., 2012,48, 11769-11771

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Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

J. Wang, S. Wang, G. Wang, J. Zhang and X. Yu, Chem. Commun., 2012, 48, 11769 DOI: 10.1039/C2CC35468C

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