Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

Ana M. García-Deibe; Cristina Portela-García; Matilde Fondo; Antonio J. Mota; Jesús Sanmartín-Matalobos

doi:10.1039/C2CC35171D

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Encapsulation of atmospheric CO₂ by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges†

Ana M. García-Deibe,^a Cristina Portela-García,^a Matilde Fondo,^a Antonio J. Mota^b and Jesús Sanmartín-Matalobos*^a

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* Corresponding authors

^a Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782-Santiago de Compostela, Spain
E-mail: jesus.sanmartin@usc.es
Fax: +34 981 528073

^b Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18002-Granada, Spain

Abstract

A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd₅O₅ crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions.

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Article information

DOI: https://doi.org/10.1039/C2CC35171D
Article type: Communication
Submitted: 18 Jul 2012
Accepted: 17 Aug 2012
First published: 20 Aug 2012

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Chem. Commun., 2012,48, 9915-9917

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Encapsulation of atmospheric CO₂ by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

A. M. García-Deibe, C. Portela-García, M. Fondo, A. J. Mota and J. Sanmartín-Matalobos, Chem. Commun., 2012, 48, 9915 DOI: 10.1039/C2CC35171D

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Chemical Communications