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Issue 80, 2012
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Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors

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Abstract

A rare anion–π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study.

Graphical abstract: Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors

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Article information


Submitted
03 Jul 2012
Accepted
23 Aug 2012
First published
04 Sep 2012

Chem. Commun., 2012,48, 9983-9985
Article type
Communication

Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors

M. Giese, M. Albrecht, T. Krappitz, M. Peters, V. Gossen, G. Raabe, A. Valkonen and K. Rissanen, Chem. Commun., 2012, 48, 9983 DOI: 10.1039/C2CC34748B

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