Issue 77, 2012
From the journal:

Chemical Communications

Cobalt(iii) complexes as functional ligands for metal (oxide) surfaces†

Rachel J. Cooper,a   Reuben T. Jane,b   Thomas E. Jeffs,a   Richard M. Hartshorn*b  and  Peter A. Tasker*a  

* Corresponding authors

a EaStCHEM School of Chemistry, The University of Edinburgh, UK
E-mail: p.a.tasker@ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 4706

b Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand
E-mail: richard.hartshorn@canterbury.ac.nz
Fax: +64 3 364 2110
Tel: +64 3 364 2874

Abstract

Co(III) polyamine complexes with either two or three labile coordination sites bind strongly to high surface area metal oxides such as goethite or aluminium trihydroxide, and have been shown to act as passivating agents for aluminium flake in aqueous media, in addition to providing a potential method for surface functionalisation.

Graphical abstract: Cobalt(iii) complexes as functional ligands for metal (oxide) surfaces

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Article information

DOI
https://doi.org/10.1039/C2CC34598F
Article type
Communication
Submitted
27 Jun 2012
Accepted
09 Aug 2012
First published
21 Aug 2012

Chem. Commun., 2012,48, 9583-9585

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Cobalt(III) complexes as functional ligands for metal (oxide) surfaces

R. J. Cooper, R. T. Jane, T. E. Jeffs, R. M. Hartshorn and P. A. Tasker, Chem. Commun., 2012, 48, 9583 DOI: 10.1039/C2CC34598F

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