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Issue 83, 2012
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Facile preparation of allylzinc species from allylboronates and zinc amidevia a boron-to-zinc exchange process and their reactions with carbonyl compounds, imines and hydrazones

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Abstract

Facile formation of allylzinc species from allylboronate and zinc amide was discovered. The boron-to-zinc exchange process occurred smoothly to afford the corresponding allylzinc amides, which were successfully employed in catalytic allylation reactions with electrophiles. Asymmetric catalysis using a chiral zinc amide is also reported.

Graphical abstract: Facile preparation of allylzinc species from allylboronates and zinc amide via a boron-to-zinc exchange process and their reactions with carbonyl compounds, imines and hydrazones

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Article information


Submitted
18 Jun 2012
Accepted
31 Aug 2012
First published
03 Sep 2012

Chem. Commun., 2012,48, 10319-10321
Article type
Communication

Facile preparation of allylzinc species from allylboronates and zinc amide via a boron-to-zinc exchange process and their reactions with carbonyl compounds, imines and hydrazones

Y. Cui, Y. Yamashita and S. Kobayashi, Chem. Commun., 2012, 48, 10319
DOI: 10.1039/C2CC34340A

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