Issue 77, 2012
From the journal:

Chemical Communications

Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes†

Amarnath Bheemaraju,a   Jeffrey W. Beattie,a   Richard L. Lord,a   Philip D. Martina  and  Stanislav Groysman*a  

* Corresponding authors

a Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA
E-mail: groysman@chem.wayne.edu
Tel: +1 313 577 2689

Abstract

The dinuclear complex Ni2L1(η2-CS2)2 (2), featuring iminopyridine ligation, is prepared by COD substitution from Ni2L1(COD)2 (1). Spectroscopic, structural, and theoretical data reveals significant activation of the metal-bound C–S bonds, as well as the different oxidation states of the iminopyridine in 1 (1−) and 2 (0).

Graphical abstract: Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

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Article information

DOI
https://doi.org/10.1039/C2CC34307J
Article type
Communication
Submitted
15 Jun 2012
Accepted
07 Aug 2012
First published
08 Aug 2012

Chem. Commun., 2012,48, 9595-9597

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Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes

A. Bheemaraju, J. W. Beattie, R. L. Lord, P. D. Martin and S. Groysman, Chem. Commun., 2012, 48, 9595 DOI: 10.1039/C2CC34307J

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