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Issue 68, 2012
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Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

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Abstract

Pyrazines and substituted pyrazines undergo addition of boron reagents having B–B, Si–B, and H–B bonds under transition-metal-free conditions, leading to high-yield synthesis of N-borylated 1,4-dihydropyrazines and 1,2,3,4-tetrahydropyrazine.

Graphical abstract: Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

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Article information


Submitted
07 Jun 2012
Accepted
04 Jul 2012
First published
05 Jul 2012

Chem. Commun., 2012,48, 8571-8573
Article type
Communication

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

K. Oshima, T. Ohmura and M. Suginome, Chem. Commun., 2012, 48, 8571
DOI: 10.1039/C2CC34086K

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