Issue 69, 2012
From the journal:

Chemical Communications

Triflimide-catalyzed allyl–allyl cross-coupling: a metal-free allylic alkylation†

Feiqing Ding,a   Ronny William,a   Fei Wanga  and  Xue-Wei Liu*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore
E-mail: xuewei@ntu.edu.sg
Fax: +65 6791 1961

Abstract

A highly efficient metal-free intermolecular C(sp3)–C(sp3) allyl–allyl cross-coupling protocol between allyl acetates and allyltrimethylsilanes, which proceeded smoothly in the presence of catalytic triflimide to form 1,5-dienes with good to excellent regioselectivity, has been developed.

Graphical abstract: Triflimide-catalyzed allyl–allyl cross-coupling: a metal-free allylic alkylation

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Article information

DOI
https://doi.org/10.1039/C2CC33641C
Article type
Communication
Submitted
21 May 2012
Accepted
09 Jul 2012
First published
10 Jul 2012

Chem. Commun., 2012,48, 8709-8711

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Triflimide-catalyzed allyl–allyl cross-coupling: a metal-free allylic alkylation

F. Ding, R. William, F. Wang and X. Liu, Chem. Commun., 2012, 48, 8709 DOI: 10.1039/C2CC33641C

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