Issue 50, 2012
From the journal:

Chemical Communications

Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers†

Ahmed M. Soliman,a   Daniel Fortin,a   Eli Zysman-Colman*a  and  Pierre D. Harvey*a  

* Corresponding authors

a Département de Chimie, Université de Sherbrooke and the Centre Québécois sur les Matériaux Fonctionnels, 2500 Boul. de l’Université, Sherbrooke, QC Canada
E-mail: pierre.harvey@uhsebrooke.ca, eli.zysman-colman@usherbrooke.ca
Fax: 819-821-8017

Abstract

The photophysical properties of [Ir]-[Pt]-[Ir]-[Pt]-[Ir] ([Ir] = [Ir(ppy)2(bpy*)]+ ([Pt] = trans-Pt(PBu3)2(C[triple bond, length as m-dash]C)2; ppyH = 2-phenylpyridine); bpy* = bipyridyl;) reveal an unprecedented triplet energy transfer from the terminal iridiums to the central Ir subunit.

Graphical abstract: Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers

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Article information

DOI
https://doi.org/10.1039/C2CC32492J
Article type
Communication
Submitted
06 Apr 2012
Accepted
30 Apr 2012
First published
30 Apr 2012

Chem. Commun., 2012,48, 6271-6273

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Unexpected evolution of optical properties in Ir–Pt complexes upon repeat unit increase: towards an understanding of the photophysical behaviour of organometallic polymers

A. M. Soliman, D. Fortin, E. Zysman-Colman and P. D. Harvey, Chem. Commun., 2012, 48, 6271 DOI: 10.1039/C2CC32492J

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