Issue 47, 2012

Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution

Abstract

We report on a heterocircuit [2]catenane in which a reversible half-rotation of one ring about the other can be induced, and locked in place, by switching the coordination of the interlocked rings between Pd(II) and Co(III).

Graphical abstract: Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution

Supplementary files

Article information

Article type
Communication
Submitted
04 Apr 2012
Accepted
21 Apr 2012
First published
24 Apr 2012

Chem. Commun., 2012,48, 5826-5828

Half-rotation in a kinetically locked [2]catenane induced by transition metal ion substitution

D. A. Leigh, P. J. Lusby, A. M. Z. Slawin and D. B. Walker, Chem. Commun., 2012, 48, 5826 DOI: 10.1039/C2CC32418K

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