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Issue 47, 2012
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The conformational locking of asparagine

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Abstract

One dominant structure has been identified analysing the rotational spectrum of asparagine in sharp contrast with the multiconformational behaviour for other amino acids with polar side chains. This locking of the conformational variety to a single conformer has been ascribed to an intramolecular hydrogen bonding network involving α-amine, α-carboxylic and amide groups.

Graphical abstract: The conformational locking of asparagine

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Article information


Submitted
22 Mar 2012
Accepted
23 Apr 2012
First published
24 Apr 2012

Chem. Commun., 2012,48, 5934-5936
Article type
Communication

The conformational locking of asparagine

C. Cabezas, M. Varela, I. Peña, S. Mata, J. C. López and J. L. Alonso, Chem. Commun., 2012, 48, 5934
DOI: 10.1039/C2CC32109B

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