Issue 45, 2012
From the journal:

Chemical Communications

Specific surface modification of the acetylene-linked glycolipid vesicle by click chemistry†

Hidehiro Ito,a   Toshiaki Kamachi*a  and  Eiji Yashima*b  

* Corresponding authors

a Department of Bioengineering, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259-B-38, Nagatsuta, Midori-ku, Yokohama 226-8501, Japan
E-mail: tkamachi@bio.titech.ac.jp
Fax: +81-45-924-5778
Tel: +81-45-924-5752

b Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan
E-mail: yashima@apchem.nagoya-u.ac.jp
Fax: +81-52-789-3185
Tel: +81-52-789-4495

Abstract

A novel glycolipid with a terminal acetylene was synthesized and used to prepare unilamellar vesicles. Using these vesicles, a convenient method was developed for the specific modification of the vesicle surface using the photoresponsive copper complex [Cu(OH2)(cage)] as the catalyst for a click reaction.

Graphical abstract: Specific surface modification of the acetylene-linked glycolipid vesicle by click chemistry

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Article information

DOI
https://doi.org/10.1039/C2CC31666H
Article type
Communication
Submitted
06 Mar 2012
Accepted
10 Apr 2012
First published
10 Apr 2012

Chem. Commun., 2012,48, 5650-5652

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Specific surface modification of the acetylene-linked glycolipid vesicle by click chemistry

H. Ito, T. Kamachi and E. Yashima, Chem. Commun., 2012, 48, 5650 DOI: 10.1039/C2CC31666H

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